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Benzyl Chloride or α-chlorotoluene SDS of Manufacturers
Anmol Chemicals is a manufacturer supplier exporter of Benzyl Chloride and it offers materials as per IP BP EP Ph Eur USP NF JP FCC Food Grade as per the the latest monograph at best prices. Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty Chemicals, Pharmaceutical Excipients, Some API, Food Chemicals in India. Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston, Chicago USA and Dubai, UAE. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, EP, USP, NF, Ph. Eur., JP, FCC or Food Grade, Analytical Reagent Grade, LR or Laboratory Reagent Grades and Pure Grades of various chemicals. All our items are analyzed to meet the required standards. We can supply the product in grams for your laboratory trial and in tons for your plant scale jobs.
We manufacture Bulk Drugs / API, Excipients, Pharmaceuticals (IP BP USP NF Ph Eur EP JP), Specialty Chemicals (Pure/Reagent), Mineral Fortifiers (FCC). Our manufacturing facility is FDA approved and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) is available. Solid materials can be customized for particle size, shape, and bulk density. We observe WHO Good Manufacturing Practices and Good Laboratory Practices. We are a government-recognized STAR Export House and "Authorised Economic Operator (AEO)" per Indian Customs.
All technical documents and DMF support available.
Benzyl Chloride or α-chlorotoluene Specifications of Manufacturers
Synonyms: Benzyl Chloride or α-chlorotoluene
CAS Number: 100-44-7, Molecular Weight: 126.58, Chemical Formula: C7H7Cl, EINECS EC Number: 202-853-6, FEMA: ----,
Benzyl Chloride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 25-Feb-26
Section 1: Product and Company Identification
Product Name & Other Names: Benzyl Chloride.
CAS No.: 100-44-7
EINECS, EC Number: 202-853-6
Molecular Weight: 126.58
Chemical Formula: C7H7Cl
Relevant uses and uses advised against (if any): Laboratory & Industrial Use.
Supplier: As per letterhead.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Skin sensitization (Category 1), H317
Serious eye damage (Category 1), H318
Acute toxicity, Inhalation (Category 3), H331
Carcinogenicity (Category 1B), H350
Specific target organ toxicity - repeated exposure, Oral (Category 2), Heart, forestomach, H373
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements  Toxic | GHS Label Elements  Corrosive | GHS Label Elements  Health Hazard |
Signal Words: Danger
Hazard statements:
H302: Harmful if swallowed.
H315: Causes Skin Irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331: Toxic if inhaled
H350 May cause cancer.
H373 May cause damage to organs (Heart, forestomach) through prolonged or repeated exposure if swallowed.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
P330: Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
C Corrosive
T Toxic
Risk Phrases:
R22 Harmful if swallowed.
R38 Irritating to skin.
R23 Toxic by inhalation.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R48 Danger of serious damage to health by prolonged exposure.
R45 May cause cancer.
Section 3: Composition / Information on Ingredients
Product Name & Other Names: Benzyl Chloride.
CAS No.: 100-44-7
EINECS, EC Number: 202-853-6
Section 4: First Aid Measures
Always seek medical attention after first aid measures are provided.
Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Emergency Medical immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Section 5: Fire Fighting Measures
It is non-flammable solid but combustible solid which burns but propagates flame with difficulty. When heated to decomposition, emits fumes. Avoid contamination with oxidizing agents. dusts may explode in the presence of an appropriate ignition source.
Protective equipment and precautions for firefighters: Firefighters should wear full firefighting turn-out gear and respiratory protection. Cool container with water spray.
Special hazards arising from the substance: Carbon oxides, Hydrogen chloride and Toxic fumes.
Suitable firefighting medium: Use water spray, dry sand, foam or dry chemical or carbon dioxide to extinguish fire. Use water spray to cool unopened containers.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.
Section 6: Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.
Section 7: Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alcohols and strong bases. Store protected from heat, sparks, and ignition sources.
Section 8: Exposure Controls / Personal Protection
Exposure guidelines: ACGIH TLV(TWA): 1 ppm; OSHA PEL(TWA): 1 ppm.
Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Use NIOSH-approved respirator with a dust cartridge.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.
Section 9: Physical and Chemical Properties
Appearance: Colorless to slightly yellow liquid.
Odor: Pungent, aromatic odor.
Odor threshold: No data found.
pH: No data found.
Relative density: about 1.1
Melting Point: -39C to -43C literature.
Initial boiling point and boiling range: 179C.
Flash point: 67C.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): Very slightly soluble in water.
Viscosity: No data found.
Section 10: Stability and Reactivity
Avoid heat and ignition sources.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Heat, strong oxidizing agents and strong bases, alcohols.
Hazardous Decomposition Products: Nitrogen oxides, Carbon oxides, Hydrogen iodide and Toxic fumes.
Hazardous Polymerization: Has not been reported.
Section 11: Toxicology Information
LD50 Oral, rat]: 560 mg/kg.
LC50 Inhalation, rat: 2 h 1,870 mg/m3.
Carcinogenicity: Probably carcinogenic to humans (Benzoyl chloride).
Reproductive toxicity: No data found.
Germ cell mutagenicity: No data found.
Specific target organ toxicity - repeated exposure: Causes damage to organs through prolonged or repeated exposure.
Section 12: Ecological Information
Toxicity to fish: static test LC50 - Danio rerio (zebra fish) - 4 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 6,1 mg/l - 48 h.
Ecotoxicity (aquatic and terrestrial): Toxic to terrestrial and aquatic plants and animals. Do not release to environment.
Persistence and degradability: Degradable.
Results of PBT and vPvB assessment: No data found.
Mobility in soil: No data found.
Section 13: Disposal Considerations
Check with all applicable local, regional, and national laws and regulations.
Section 14: Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN-No: UN 1738
Proper Shipping Name: Benzyl chloride.
Hazard Class: 6.1 (8); Packing Group: II.
IATA
UN-No: UN 1738
Proper Shipping Name: Benzyl chloride.
Hazard Class: 6.1 (8); Packing Group: II.
IMDG/IMO
UN-No: UN 1738
Proper Shipping Name: Benzyl chloride.
Hazard Class: 6.1 (8); Packing Group: II.
Section 15: Regulatory Information
USA:
SARA 311/312 Hazard Categories: See section 2.
California Proposition 65: Not listed for Cancer, Reproductive Harm etc.
Section 16: Other Information
European Labeling in Accordance with EC Directives:
H302 Harmful if swallowed.
H315 Causes Skin Irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled
H350 May cause cancer.
H373 May cause damage to organs (Heart, forestomach) through prolonged or repeated exposure if swallowed.
H410 Very toxic to aquatic life with long lasting effects.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
C Corrosive
T Toxic
Risk Phrases:
R22 Harmful if swallowed.
R38 Irritating to skin.
R23 Toxic by inhalation.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R48 Danger of serious damage to health by prolonged exposure.
R45 May cause cancer.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Keywords: Benzyl Chloride or α-chlorotoluene IP BP Ph Eur EP USP Analytical Reagent FCC Food Grade CAS Number 100-44-7 Manufacturer Supplier Exporter Monograph Uses Chemical Molecular Formula Weight.
Manufacturer Supplier Exporter
ANMOL CHEMICALS Private Limited
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) +91 22 23726950, +91 22 23774610, +91 22 23723564
Taloja Navi Mumbai, Banglore, INDIA
e-mail: info@anmol.org
Copyright and Usual Disclaimer is Applicable
Last updated 25-feb-26
Exporters to USA, Canada, UAE, Kuwait, Qatar, Gautemala, Tunisia, Europe, South Africa, Bangladesh, Sri Lanka, Tanzania, Kenya, Egypt, Iraq, Turkey, Israel, Vietnam, Nigeria, Uganda, Brazil, Chile, Argentina, Dubai, UAE, Saudi Arabia, Cameroon, Mexico, Brazil, Chile, Argentina, Korea, Thailand, Malaysia, Indonesia, Jakarta, Australia, China, Germany, France, etc.
Representatives in New York, Houston - Texas, Chicago - Illinois, Los Angeles.
All products are Sold for Industrial and Laboratory Use only.
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Benzyl Chloride
α-chlorotoluene Manufacturers